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Hirota, Koichi; Kojima, Takuji
Bulletin of the Chemical Society of Japan, 78(9), p.1685 - 1690, 2005/09
Times Cited Count:7 Percentile:31.71(Chemistry, Multidisciplinary)Decomposition behavior under electron-beam irradiation was examined for polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) isomers in incinerator gases. Significant decomposition was obtained for all PCDD isomers over the investigated absorbed doses, which was resulted from oxidation reactions with OH radicals yielded by electron-beam irradiation. In the case of PCDFs, specific isomers having symmetrical structures such as 1, 2, 8, 9-, 2, 3, 7, 8-, and 3, 4, 6, 7-TeCDFs were yielded through the dechlorination of PeCDF isomers. Thermal electrons probably played a role in the dechlorination of PeCDF isomers.